While  many topically applied vitamins have skin benefits, none can come  close to the wide ranging salubrious effects provided by Vitamin A, a  powerful and multifunctional oily nutrient that is available in three  major forms.
The  most common and the most stable form of Vitamin A is called retinyl  palmitate. Retinyl is the Latin designation for Vitamin A and  palmitate represents a carrying case or ferry for Vitamin A, acting  to shuttle to the nutrient around in a protective bubble.  This is  the type that is absorbed into the body from the digestive system  when we take supplements or eat Vitamin A containing foods.   Topically it has some nice moisturizing and skin softening properties  and there are enzymes in the skin that can break it down and activate  it.
 The  second form of Vitamin A is known as retinol. It’s more active than  retinyl palmitate and, in fact, if you use a high enough  concentration of retinol (say 5 to 10 or even 20 percent) you can get  a nice exfoliating Vitamin A skin peel.  However retinol is quite  unstable and for this reason you’re really not going to find these  kinds of concentrations in topical products.  At lower concentrations  retinol can be “somewhat effective”, although the amount of  retinol in most retail products isn’t going to get you much effect.